Chemical ingredients are casually accepted by consumers because the terminology and the science are so complex that even scientists argue over the impact on people and the environment. But it is important for citizens -- parents, loved ones, and merchants who care about their customers -- to learn as much as possible about key ingredients. That's what the green movement is about -- and that is what social justice is about. Pollutants can be recognized and removed from our homes and work environments.
Here is a basic overview of one set of known problem chemicals: organic bromine and chlorine. Better known as substances in PVC pipe, electronics and other common product materials.
This overview of organic bromine and chlorine is quoted from a report by the International Chemical Secrtariat (www.chemsec.org) and Clean Production Action (www.cleanproduction.org)
Organic bromine and chlorine
Compounds that contain organic bromine and chlorine tend
to be particularly likely to bioaccumulate, be persistent and/or
toxic - or to degrade in the environment into new brominated
or chlorinated organic compounds with these characteristics.
As
they accumulate over time, these organo-halogen compounds
can become widespread pollutants in air, water, soil, and sediment,
where they are increasingly ingested by humans and
animals. It is also important to note that inorganic forms of
these chemicals can lead to the formation of dioxin and other
problematic chemicals, particularly when they are mixed with
organic matter.
Chlorinated dioxins and furans can cause severe health problems,
including:
- Cancer
- Endocrine disruption
- Endometriosis
- Neurological damage
- Birth defects and impaired child development
- Reproductive system damage
- Immune system damage
Because dioxins and furans break down slowly, they endure in
the environment for long periods of time.18,19 Like many organohalogens,
they bioaccumulate in animals' fatty tissue. The highest
concentrations are found in animals at the top of the food
chain, including humans. Linda Birnbaum, a leading science
expert on BFR s and dioxins, led the US EPA's 1994 dioxin assessment
process, which concluded that for certain dioxins there
was no safe level of exposure for humans.
Most of what we
know about dioxins and furans is the result of the study of one
particular dioxin: tetrachlorodibenzo-p-dioxin (TCD ),
which is a developmental toxicant that causes skeletal deformities,
kidney defects, and weakened immune responses in the
offspring of animals exposed to it during pregnancy. The compound
is also associated with some cancers and other health
effects, including immune system alterations and skin lesions.
Additionally, studies indicate many of the hundreds of other
dioxins and furans are likely to cause similar health effects.
Dioxin precursors
Of particular concern is the ability of halogenated organics to
act as precursors for generating dioxin, a potent known human
carcinogen4 that is toxic at very low levels. Exposing halogenated
organics such as the BFR s, CFR s, and PVC in electronics to
incineration at insufficiently high temperatures or the uncontrolled
burning practices commonly used in informal recycling
in the developing world can generate dioxins, as well as furans,
which can be equally toxic.
Chlorine Use in PVC
The predominant use of chlorine in electronics has been in PVC
plastics. Most internal and external cables use PVC to insulate
copper wires. Human health and environmental concerns about
exposure to plastic additives used in PVC, such as lead, cadmium,
and phthalates, as well as dioxin formation during the combustion of PVC components, triggered industry-wide efforts
to replace PVC use in wire and cables. The major challenge has
been developing alternative resins, that meet safety standards
that in some instances were only written to specify PVC resins.
To further complicate the situation, these safety standards vary
geographically, forcing companies to use and get approval for
multiple alternatives that comply with the different regional
standards.
Bromine- and chlorine- based compounds are used
extensively in the production of today's modern electronic
products as flame retardants, solvents, dyes,
adhesives and plastic resins.
The highest concentrations
of bromine and chlorine are used in brominated
and chlorinated flame retardants (BFR s and CFR s) and
polyvinyl chloride (PVC).
However, in response to growing
awareness of the human health and environmental
problems associated with the use of bromine and
chorine, leading manufacturers have started to restrict
the use of these chemicals. These manufacturers have
also come to recognize that the wide variety of halogenated
compounds used in the electronics supply
chain makes it very difficult to certify that specific brominated
or chlorinated compounds have successfully
been removed from electronics products.
Accordingly,
some manufacturers have chosen to restrict the use
of all substances containing these two elements,
rather than contend with the difficulties involved in
implementing and validating restrictions on specific,
individual brominated and chlorinated substances.
The method of focusing on chemicals on the group
level rather than on individual compounds has come
to be known as the elemental approach.
The Association Connecting Electronics Industries (IPC) is currently
in the process of developing another standard for all
plastic resins. The current proposal (September 2009) applies
the elemental standard to a subset of brominated and chlorinated
compounds, namely BFR s, CFR s, PVC, and PVC congeners in
plastic resins. This approach, however, is more difficult to verify
through testing and some companies are calling for a more
verifiable approach that would apply restrictions on all uses of
bromine and chlorine.